Physical Review Letters
We report the first magnetocaloric and calorimetric observations of a magnetic-field-induced phase transition within a superconducting state to the long-sought exotic Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) superconducting state, first predicted over 50 years ago. Through the combination of bulk thermodynamic calorimetric and magnetocaloric measurements in the organic superconductor κ−(BEDT−TTF)2Cu(NCS)2 as a function of temperature, magnetic field strength, and magnetic field orientation, we establish for the first time that this field-induced first-order phase transition at the paramagnetic limit Hp is a transition to a higher-entropy superconducting phase, uniquely characteristic of the FFLO state. We also establish that this high-field superconducting state displays the bulk paramagnetic ordering of spin domains required of the FFLO state. These results rule out the alternate possibility of spin-density wave ordering in the high-field superconducting phase. The phase diagram determined from our measurements—including the observation of a phase transition into the FFLO phase at Hp—is in good agreement with recent NMR results and our own earlier tunnel-diode magnetic penetration depth experiments but is in disagreement with the only previous calorimetric report.
Specific heat, Superconductivity, Phase transitions, Specific phase transitions, Superconducting phase transition
© 2017 American Physical Society
Agosta, Charles C.; Fortune, Nathanael Alexander; Hannahs, Scott T.; Gu, Shuyao; Liang, Lucy; Park, Ju-Hyun; and Schleuter, John A., "Calorimetric Measurements of Magnetic-Field-Induced Inhomogeneous Superconductivity Above The Paramagnetic Limit" (2017). Physics: Faculty Publications. 22.