Ligand Effects in Homogeneous Au Catalysis

Authors

David J. Gorin, University of California, BerkeleyFollow
Benjamin D. Sherry, University of California, Berkeley
F. Dean Toste, University of California, Berkeley

Document Type

Article

Publication Date

8-1-2008

Publication Title

Chemical Reviews

Abstract

The solutions with the problems regarding the ligand effects in homogeneous catalysis through December 2007 has been given. Specifically, the problems with the obvious differences in reactivity and selectivity that comes from changing neutral or anionic ligands will be addressed with a focus on ligands and complexes that enables enantioselective catalysis. There are at times when catalyst choice gives off better improvement within the reaction yields or efficiencies. Meanwhile, an emphasis will be given on the privileged ligands and catalysts for a given class of reactions. Finally, the Hayashi/Ito asymmetric aldol reaction will be dealt with.

Volume

108

Issue

8

First Page

3351

Last Page

3378

DOI

10.1021/cr068430g

ISSN

00092665

Rights

© 2008 American Chemical Society

Comments

Peer reviewed accepted manuscript.

Recommended Citation

Gorin, David J.; Sherry, Benjamin D.; and Toste, F. Dean, "Ligand Effects in Homogeneous Au Catalysis" (2008). Chemistry: Faculty Publications, Smith College, Northampton, MA.
https://scholarworks.smith.edu/chm_facpubs/65